- Prof. Tijjani Bande (Kebbi State) – Ambassador/Representative to the Permanent Mission of Nigeria to the United Nations Headquarters in New York
- Itegboje S. Sunday (Edo State) – Nigeria’s Ambassador/Deputy Representative, Permanent Mission of Nigeria to the United Nations Headquarters in New York
- Kadiri Ayinla Audu (Kwara State) – Ambassador/Representative to the Permanent Mission of Nigeria to the United Nations Offices in Geneva
- Bankole Adegboyega Adeoye (Ogun State) – Ambassador/Representative to the Embassy of Nigeria/Permanent Mission to the African Union in Addis Ababa
*Career diplomats *Non-Career diplomats